polyurethane adhesives being applied to car glazing

Polyurethane adhesives and sealants

Polyurethane adhesives and sealants among the most used systems

Polyurethane (PUR) systems are among the most used adhesives, sealants and adhesive sealants due to their unique properties and the possibility to give them other characteristics through modification. Polyurethane adhesives and sealants are best known for the elasticity of seams and bonds they create. However, polyurethanes also exist as tougher rigid formulations which are more common as adhesives only.

One of the greatest reasons for the popularity of polyurethane adhesives and sealants is the fact that they adhere to almost any surface regardless its porosity. Polyurethane sealants and glues can also be applied in challenging environments and tricky locations.

Advantages of PUR adhesive and sealant systems

Polyurethane adhesives and sealants exist as single and multicomponent systems which can be elastic or rigid depending on the formulation. Note that the rigid systems are excellent PUR adhesive systems, whereas elastic systems are common polyurethane sealants and glues as well as PU adhesive sealant systems.

  • Curing in challenging environments: polyurethane adhesives and sealants are either heat or moisture curing. Therefore, ambient humidity can be very high as the system only cures faster when moisture is involved. Polyurethane sealant and adhesive systems also generally cure even if the ambient temperature fluctuates or shifts towards extremes. This can vary per product.
  • Suitable for numerous materials: polyurethane bonds and seals porous and nonporous materials including metals, wood, concrete, most plastics, rubber, cured epoxy, leather, glass and many more. PUR adhesive and sealant systems are also suitable for bonding dissimilar materials. Note that most polyurethanes should not be applied to polypropylene, polyethylene, silicone or surfaces coated with Teflon or other fluoropolymers.
  • Waterproof: polyurethane sealants and glues are generally waterproof, however, the water resistance varies per composition. Most systems resist water enough to cause no problems in exterior construction applications. Nonetheless, polyurethane adhesives and sealants are not recommended for full immersion underwater.
  • Environmentally friendly: polyurethane offers sometimes a more environmentally friendly alternative: for example timber lamination can be carried out with PUR adhesives instead of systems that contain formaldehyde. PUR adhesive and sealant systems are generally solvent free and have zero to very low VOC value. Also food safe polyurethane sealants and adhesives exist.
  • Stress absorption and vibration damping: especially the elastic polyurethane adhesives and sealants absorb stresses and damp vibration and noise. Therefore, they are commonly applied in vehicles, for example in transport vehicle glazing and cabins of agricultural machinery. In these applications also PU adhesive sealant systems are common.
  • Paintability: to increase aesthetic appeal or protect seams and bonds from factors like UV radiation, PUR adhesives and sealants can be painted. Acrylic paints are the most suitable for the job.

Considerations regarding PUR adhesive and sealant systems

Even though polyurethanes have many benefits that often make them the preferred choice, they are not flawless. Some factors that must be considered when working with polyuretahne sealants and adhesives are as follows.

  • Strength: polyurethane forms strong joints yet they are not comparable to those formed by epoxy adhesives and sealants. Especially when bonding metal to metal, epoxy is likely to deliver stronger results.
  • Contains isocyanates: isocyanate groups are a crucial part of polyurethane formulation. However, they are toxic and require additional safety measures when processed. Nevertheless, once the polyurethane is cured, isocyanate is not a hazard.
  • Short pot life/ skin formation time: working with polyurethane adhesives and sealants requires speed as the curing process starts quickly. When working with 2K polyurethane adhesives or sealants, the pot life must be kept in mind as the reaction starts as soon as the components are mixed. On the other hand, the skin formation of 1K products can also start fast.

Types of polyurethane adhesives

The two most common adhesive types are epoxy and polyurethane. The latter is more flexible when it comes to modifying the bonding systems. Polyurethane adhesive exists as one and two component systems which can be either elastic or rigid depending on the composition. The single component polyurethanes are generally easier to work with as they do not require mixing prior to application. On the other hand, 2K polyurethane adhesive systems tend to be stronger and have more desired physical properties.

Single component moisture curing polyurethane adhesive

polyurethane adhesives applied in construction
Single component moisture curing polyurethane adhesives are common as general purpose glues in interiors and exteriors.

Moisture curing polyurethane adhesives are predominantly single component systems which require moisture in order to set. Prior to application, these adhesives are sticky, and they cure into a bond which remains elastic. Therefore, these polyurethane adhesive glue systems are often used for applications such as glazing and construction.

When working with moisture curing polyurethane adhesives, it is important to consider the skin formation time of the adhesive. As soon as the PUR adhesive comes into contact with the moisture in the air, a skin starts forming. The skin formation time is the time one has to work the glue.

Single component heat curing PUR adhesive

The other type of one component polyurethane glue cures when heat from external source is applied. This type of adhesive forms rigid bonds and is generally stronger than its moisture curing alternative. However, it is not as strong the 2K rigid PUR adhesive, which is why the 1K systems are often used in simple assembly applications.

Rigid heat curing polyurethane glues can be processed faster than moisture curing adhesives as the speed of curing process can be controlled with heat. With rigid adhesives, thick layers should be avoided as the curing starts from the outside. The thicker the layer, the greater the chance the inside is not completely cured.

2K polyurethane adhesive systems

Two component polyurethane adhesives can be either rigid or elastic depending on the chemical composition. The elastic 2K polyurethane glues are thermoplastics meaning that they can be reworked when heated. The rigid adhesives, for their part, are thermosets, which means that once cured, reworking is not possible.

Multicomponent polyurethane adhesive systems can be modified more easily than the single component alternatives. Therefore, they can be given more physical properties and are used throughout industries in applications varying from printed wiring boards to vehicle glazing and interior trim. Contact us for more information on the possibilities with 2K polyurethane adhesive.

About polyurethane sealants

Also, when it comes to sealants, polyurethane is the most common choice next to silicone. The two types of sealants are both flexible allowing for up to 50% movement and they keep water and air out. However, they also have differences: polyurethane sealant is organic and silicone is inorganic.

Due to their organic nature, polyurethane sealants tend to be less durable than silicone. They are often given a life span of 5 to 10 years whereas silicone can reach the double. However, this can also be seen in the price: polyurethane sealant is usually about a half the price of silicone. If you are looking for a product that has the beneficial properties of both silicone and polyurethane sealants, take a look at silane modified polymer products.

Note that if you wish to replace a silicone seam with polyurethane sealant, or vice versa, make sure to remove all of the sealant before applying another one. If the sealant is not properly removed, the new sealant is likely to adhere poorly.

Looking for polyurethane sealants or adhesives?

As polyurethane glues and sealants can be modified rather easily, they are sometimes found in surprising applications. Therefore, in case you are looking for a suitable sealant or adhesive for your project or product, considering polyurethane might be worth your while. For more information on the possible applications, hit the button below and contact us. Our experts are determined to find the best bonding and sealing solutions for each application.

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